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ChemicalBook--->CAS DataBase List--->1040274-10-9

1040274-10-9

1040274-10-9 Structure

1040274-10-9 Structure
IdentificationBack Directory
[Name]

(S)-(-)-7[4(S)-(Benzyl)oxazol-2-yl]-7-di(3,5-di-t-butylphenyl)phosphino-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Sa,S)-DTB-Bn-SIPHOX
[CAS]

1040274-10-9
[Synonyms]

(Sa,S)-DTB-Bn-SIPHOX
(Sa,S)-7-[4-(Benzyl)oxazol-2-yl]-7′-di(3,5-ditertbutylphenyl)phosphinyl-1,1′-spirobiindane
(S,S)-7-[4-(Benzyl)oxazol-2-yl]-7′-di(3,5-ditertbutylphenyl)phosphinyl-1,1′- spirobiindane
(S)-(-)-7[4(S)-(Benzyl)oxazol-2-yl]-7-di(3,5-di-t-butylphenyl)phosphino-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Sa,S)-DTB-Bn-SIPHOX
Oxazole,2-[(1S)-7'-[bis[3,5-bis(1,1-dimethylethyl)phenyl]phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-inden]-7-yl]-4,5-dihydro-4-(phenylmethyl)-,(4S)-
[Molecular Formula]

C55H66NOP
[MDL Number]

MFCD17018765
[MOL File]

1040274-10-9.mol
[Molecular Weight]

788.092
Chemical PropertiesBack Directory
[Melting point ]

159-161°C
[alpha ]

-185.6° (c 0.5, CH2Cl2)
[form ]

solid
[color ]

white
[Sensitive ]

moisture sensitive
Questions And AnswerBack Directory
[Reaction]

  1. Chiral ligands for the iridium-catalyzed, asymmetric hydrogenation of imines.
  2. Chiral ligands for the iridium-catalyzed, asymmetric hydrogenation of α-β unsaturated carboxylic acids.
  3. Chiral ligands for iridium-catalyzed, asymmetric hydrogenation of α,-oxy-α,β-unsaturated carboxylic acids
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