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ChemicalBook--->CAS DataBase List--->104439-77-2

104439-77-2

104439-77-2 Structure

104439-77-2 Structure
IdentificationBack Directory
[Name]

SHVO'S CATALYST
[CAS]

104439-77-2
[Synonyms]

Shvo Catalyst
SHVO'S CATALYST
1-HYDROXYTETRAPHENYL-CYCLOPENTADIENYL(TE
1-HYDROXYTETRAPHENYLCYCLOPENTADIENYL(TETRAPHENYL-2,4-CYCLOPENTADIEN-1-ONE)-HYDROTETRACARBONYLDIRUTHENIUM (II)
1-HYDROXYTETRAPHENYLCYCLOPENTADIENYL(TETRAPHENYL-2,4-CYCLOPENTADIEN-1-ONE)-1-HYDROTETRACARBONYLDIRUTHENIUM(II)
1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-u-hydrotetracarbonyldiruthenium(II)
1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)
1-Hydroxytetraphenylcylclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldirutheniuM(II)
1-Hydroxytetraphenylcylclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-Mu-hydrotetracarbonyldirutheniuM(II)
1-HYDROXYTETRAPHENYL-CYCLOPENTADIENYL(TETRAPHENYL-2,4-CYCLOPENTADIEN-1-ONE)-MU-HYDROTETRACARBONYLDIRUTHENIUM(II)
1-HYDROXYTETRAPHENYLCYCLOPENTADIENYL(TETRAPHENYL-2,4-CYCLOPENTADIEN-1-ONE)--HYDROTETRACARBONYLDIRUTHENIUM (II) 98%
1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-^M-hydrotetracarbonyldirutheniuM(II), 98%
1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldirutheniuM(II) SHVO'S CATALYST
1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II),98%SHVO'SCATALYST
1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II), 98% SHVO'S CATALYST
TETRACARBONYL-MU-HYDRO[(1,2,3,4,5-H)-1-HYDROXYLATO-2,3,4,5-TETRAPHENYL-2,4-CYCLOPENTADIEN-1-YL][(1,2,3,4,5-H)-1-HYDROXY-2,3,4,5-TETRAPHENYL-2,4-CYCLOPENTADIEN-1-YL]DIRUTHENIUM
Ruthenium,tetracarbonyl-m-hydro[(1,2,3,4,5-h)-1-hydroxylato-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl][(1,2,3,4,5-h)-1-hydroxy-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl]di-
Shvos Catalyst, Tetracarbonyl-μ-hydro[(1,2,3,4,5-H)-1-hydroxylato-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl][(1,2,3,4,5-H)-1-hydroxy-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl]diruthenium
[Molecular Formula]

C62H41O6Ru2 5*
[MDL Number]

MFCD03840556
[MOL File]

104439-77-2.mol
[Molecular Weight]

1084.13
Chemical PropertiesBack Directory
[Melting point ]

223-227 °C
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

DMSO (Slightly)
[form ]

Powder
[color ]

orange
[Water Solubility ]

Soluble in water and polar organic solvents.
[Sensitive ]

Moisture Sensitive
[Merck ]

14,8483
[CAS DataBase Reference]

104439-77-2
Hazard InformationBack Directory
[Uses]

Catalyst in organic syntheses for hydrogen transfers including disproportionation of aldehydes, reduction of ketones and aldehydes, oxidation and/or racemization of alcohols and amines.
[reaction suitability]

core: ruthenium
reagent type: catalyst
Safety DataBack Directory
[Safety Statements ]

22-24/25
[WGK Germany ]

3
[HS Code ]

2843.90.0000
Questions And AnswerBack Directory
[Reactions]

  1. In conjugation with lipase, ruthenium catalyst used in the asymmetric transformation of ketones and enol acetates into chiral acetates.
  2. Dynamic kinetic resolution resulting from the ruthenium catalyzed racemization of enzymatically- resolved substrates.
  3. Conversion of secondary amines to primary amines in the presence of ammonia.
  4. Co-catalyt for aerobic lactonization of diols. 
Reactions of 104439-77-2
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