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ChemicalBook--->CAS DataBase List--->117337-19-6

117337-19-6

117337-19-6 Structure

117337-19-6 Structure
IdentificationBack Directory
[Name]

Methyl 2-[2-chloro-4-fluoro-5-[(3-oxo-5,6,7,8-tetrahydro-[1,3,4]thiadiazolo[3,4-a]pyridazin-1-ylidene)amino]phenyl]sulfanylacetate
[CAS]

117337-19-6
[Synonyms]

kih-9201
Hsdb 7270
FLUTHIACET-METHYL
Eluthiacet-methyl
Fluthiacet-methyl [iso]
Fluthiacet-methyl Solution
1000 μg/mL in Acetonitrile
Fluthiacet-methyl Standard
fluthiacet-methyl (bsi, pa iso)
Fluthiacet-methyl Solution, 1000ppm
Fluthiacet-methyl Solution in Methanol, 100μg/mL
Methyl 2-[2-chloro-4-fluoro-5-[(3-oxo-5,6,7,8-tetrahydro-[1,3,4]thiadiazolo[3,4-a]pyridazin-1-yliden
Methyl 2-[2-chloro-4-fluoro-5-[(3-oxo-5,6,7,8-tetrahydro-[1,3,4]thiadiazolo[3,4-a]pyridazin-1-ylidene)amino]phenyl]sulfanylacetate
Methyl {2-chloro-4-fluoro-5-[(EZ)-5,6,7,8-tetrahydro-3-oxo-1H,3H-[1,3,4]thiadiazolo[3,4-a]pyridazin-1-ylideneamino]phenylthio}acetate
[[2-Chloro-4-fluoro-5-[(tetrahydro-3-oxo-1H,3H-[1,3,4]thiadiazolo [3,4-a]pyridazin-1-ylidine)amino]phenyl]thioacetic acid methyl ester
Acetic acid, ((2-chloro-4-fluoro-5-((tetrahydro-3-oxo-1H,3H-(1,3,4)thiadiazolo(3,4-A)pyridazin-1-ylidene)amino)phenyl)thio)-, methyl ester
Acetic acid, 2-[[2-chloro-4-fluoro-5-[(tetrahydro-3-oxo-1H,3H-[1,3,4]thiadiazolo[3,4-a]pyridazin-1-ylidene)amino]phenyl]thio]-, methyl ester
[Molecular Formula]

C15H15ClFN3O3S2
[MDL Number]

MFCD03792701
[MOL File]

117337-19-6.mol
[Molecular Weight]

403.88
Chemical PropertiesBack Directory
[Melting point ]

104.6°
[Boiling point ]

503.5±60.0 °C(Predicted)
[density ]

1.57±0.1 g/cm3(Predicted)
[storage temp. ]

0-6°C
[form ]

neat
[pka]

-2.86±0.20(Predicted)
[BRN ]

11510131
[EPA Substance Registry System]

Fluthiacet-methyl (117337-19-6)
Safety DataBack Directory
[Hazard Codes ]

Xi,N
[Risk Statements ]

36-50
[Safety Statements ]

26-61
[RIDADR ]

UN 3077 9 / PGIII
[WGK Germany ]

3
[HS Code ]

29309090
[Hazardous Substances Data]

117337-19-6(Hazardous Substances Data)
[Toxicity]

LD50 in rats (mg/kg): >5000 orally; >2000 dermally (Miyazawa)
Hazard InformationBack Directory
[Uses]

Herbicide.
[Definition]

ChEBI: Fluthiacet-methyl is a methyl ester resulting from the formal condensation of the carboxy group of fluthiacet with methanol. A proherbicide for fluthiacet, it is used for the control of broad-leaved weeds in crops such as maize and soya. It has a role as an agrochemical, an EC 1.3.3.4 (protoporphyrinogen oxidase) inhibitor and a proherbicide. It is an organic sulfide, a methyl ester, a member of monochlorobenzenes, a member of monofluorobenzenes and a thiadiazolopyridazine. It is functionally related to a fluthiacet.
[Metabolic pathway]

Fluthiacet methyl is converted to its isomer, urazole, by glutathione S-transferase (GST) and glutathione (GSH) from some plants and rat liver microsomes. Fluthiacet methyl inhibits Protox (protoporphyrinogen oxidase) activity after conversion to the corresponding urazole by GST and GSH. Fluthiacet methyl is chemically converted to urazole with a thiol anion in media by the nucleophilic reaction. It is also suggested that a free acid of urazole, desulfated urazole, and the oxidative ring-cleaved formyl degradation products result from hydrolysis with esterase from soybean seedlings.
When fluthiacet methyl is administered orally to rats in a single dose, 63-85% of the dose is excreted in the feces and 10-23% in the urine, respectively, after 48 h. The main metabolite is the isomer of fluthiacet methyl (urazole) which is also identified in the soil degradation products. Monohydroxylated products on the pyridazine ring are identified as metabolites by rats only.
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