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ChemicalBook--->CAS DataBase List--->1442433-71-7

1442433-71-7

1442433-71-7 Structure

1442433-71-7 Structure
IdentificationBack Directory
[Name]

9-Mesityl-10-methylacridinium tetrafluoroborate
[CAS]

1442433-71-7
[Synonyms]

Acr-Mes]+(BF4)-
9-Mesityl-10-methylacridinium tetrafluoroborate
9-mesityl-10-methylacridin-10-ium tetrafluoroborate
[Molecular Formula]

C23H22BF4N
[MOL File]

1442433-71-7.mol
[Molecular Weight]

399.232
Chemical PropertiesBack Directory
[Melting point ]

>80°C (dec.)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Solid
[color ]

Yellow to Dark Yellow
[Stability:]

Hygroscopic
[InChI]

InChI=1S/C23H22N.BF4/c1-15-13-16(2)22(17(3)14-15)23-18-9-5-7-11-20(18)24(4)21-12-8-6-10-19(21)23;2-1(3,4)5/h5-14H,1-4H3;/q+1;-1
[InChIKey]

KKMWMXQQOIIJIZ-UHFFFAOYSA-N
[SMILES]

C1C2=C([N+](C)=C3C(=C2C2=C(C)C=C(C)C=C2C)C=CC=C3)C=CC=1.[B-](F)(F)(F)F
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

9-Mesityl-10-methylacridinium Tetrafluoroborate can be used for the synthesis of?γ-butyrolactones, γ-lactams and pyrrolidines. 9-Mesityl-10-methylacridinium Tetrafluoroborate has been reported by Nicewicz et al. to mediate myriad transformations through Photoredox Catalysis. The applications include the anti-Markovnikov hydroamination of alkenes and addition of carboxylic acids to alkenes and the hydrotrifluoromethylation of styrenes using the Langlois reagent S673690.
[reaction suitability]

core: acridinium
reaction type: Photocatalysis
reagent type: catalyst
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