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ChemicalBook--->CAS DataBase List--->17587-33-6

17587-33-6

17587-33-6 Structure

17587-33-6 Structure
IdentificationBack Directory
[Name]

FEMA 3766
[CAS]

17587-33-6
[Synonyms]

FEMA 3766
2,6-Nonadienal
T2 T6 NONADIENAL
(e,e)-6-nonadienal
(2E,6E)-2,6-Nonadienal
2,6-Nonadienal, (E,E)-
(2E,6E)-nona-2,6-dienal
2,6-Nonadienal, (2E,6E)-
2,6-trans,trans-Nonadienal
2-trans-6-trans-Nonadienal
(2E,6E)-nona-2,6-dien-1-al
TRANS 2 TRANS 6-NONADIENAL
TRANS, TRANS-2,6-NONADIENAL
TRANS-2,TRANS-6-NONADIEN-1-AL
trans-2,trans-6-Nonadienal,95%
TRANS TRANS-2 6-NONADIENAL 93+%
[EINECS(EC#)]

241-557-1
[Molecular Formula]

C9H14O
[MOL File]

17587-33-6.mol
[Molecular Weight]

138.21
Chemical PropertiesBack Directory
[Appearance]

clear colorless to pale yellowish liquid
[Boiling point ]

57 °C0.6 mm Hg(lit.)
[density ]

0.875 g/mL at 25 °C(lit.)
[FEMA ]

3766 | 2-TRANS-6-TRANS-NONADIENAL
[refractive index ]

n20/D 1.471(lit.)
[Fp ]

189 °F
[storage temp. ]

0-6°C
[solubility ]

Practically insoluble in water, soluble in alcohol, Propylene glycol and oils.
[form ]

Almost colourless or very pale yellowish oil.
[Odor]

at 1.00 % in dipropylene glycol. fresh citrus green cucumber melon
[biological source]

synthetic
[Odor Type]

green
[JECFA Number]

1187
[LogP]

2.60
[EPA Substance Registry System]

2,6-Nonadienal, (2E,6E)- (17587-33-6)
Hazard InformationBack Directory
[Chemical Properties]

clear colorless to pale yellowish liquid
[Description]

2-trans-6-trans.Nonadienahas a tallowy odor.
[Occurrence]

Reported found in soybean oil, beef tallow, cold-stored butter, mango, lingonberry, cucumber, corn mint oil, lean fish, beer, trassi, buckwheat, shrimp and rooibus tea (Aspalathus linearis).
[Uses]

(2E,6E)-2,6-Nonadienal is a useful building block for organic synthesis.
[Application]

2-trans, 6-trans-Nonadienal would particularly be used in imitation Cucumber and as a trace ingredient in many green and fruity flavour types.
[Production Methods]

Most methods start with 3-Hexenol. 1) via Hexenyl iodide and its Grignard compound, with Acrolein to the carbinol. By treatment with Phosphorous tribromide and saponification is obtained the alcohol Nonadienol which can be oxidized to 2-trans, 6-trans-Nonadienal by Chromic acid oxidation. 2) from Dipropargyl via Octadi-yne to Nonadiynal-diethylacetal, followed by selective hydrogenation to Nonadienal diethylacetal which yields 2-trans, 6-trans-Nonadienal by acid hydrolysis.
[Aroma threshold values]

Detection: 0.09 ppb
[Taste threshold values]

Taste characteristics at 1 ppm: fresh, green cucumber skin and watermelon with a fatty nuance
Safety DataBack Directory
[Safety Statements ]

24/25
[WGK Germany ]

3
[RTECS ]

RA5391720
Spectrum DetailBack Directory
[Spectrum Detail]

FEMA 3766(17587-33-6)FT-IR
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