| Identification | Back Directory | [Name]
6,7-DIBROMOBENZO(1,4)DIOXAN | [CAS]
25812-80-0 | [Synonyms]
6,7-DIBROMOBENZO(1,4)DIOXAN
6,7-dibromo-2,3-dihydro-1,4-benzodioxine
1,4-Benzodioxin, 6,7-dibromo-2,3-dihydro-
6,7-Dibromo-2,3-dihydrobenzo[b][1,4]dioxine | [Molecular Formula]
C8H6Br2O2 | [MDL Number]
MFCD00463506 | [MOL File]
25812-80-0.mol | [Molecular Weight]
293.94 |
| Chemical Properties | Back Directory | [Melting point ]
139.6-140.0 °C | [Boiling point ]
314.3±42.0 °C(Predicted) | [density ]
1.950±0.06 g/cm3(Predicted) | [storage temp. ]
Room temperature. | [Appearance]
Off-white to yellow Solid |
| Hazard Information | Back Directory | [Synthesis]
GENERAL METHOD: A mixture of 1,4-benzodioxane (0.5 mmol), iodine pentoxide (334 mg, 1.0 mmol) and potassium bromide (148 mg, 1.25 mmol) was dissolved in 2 mL of water. The reaction was stirred at room temperature until completion. Upon completion of the reaction, the mixture was extracted with ethyl acetate and the extract was subsequently concentrated under reduced pressure. Finally, the mixture was purified by fast column chromatography (silica gel) to afford 6,7-dibromo-2,3-dihydrobenzo[b][1,4]dioxohexene. | [References]
[1] Tetrahedron, 2004, vol. 60, # 40, p. 8899 - 8912
[2] European Journal of Organic Chemistry, 2012, # 33, p. 6586 - 6593
[3] Synthetic Communications, 2014, vol. 44, # 2, p. 181 - 187
[4] Tetrahedron, 2007, vol. 63, # 51, p. 12621 - 12628
[5] Journal of the Chemical Society, 1915, vol. 107, p. 1595 |
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| Company Name: |
Energy Chemical
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021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
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