| Identification | Back Directory | [Name]
1-IODO-2-NITRO-4-CHLOROBENZENE | [CAS]
5446-05-9 | [Synonyms]
NSC 17163
5-Chloro-2-iodonitrobenzene
4-Chloro-2-nitrophenyl iodide
4-choro-1-iode-2-nitrobenzene
1-IODO-2-NITRO-4-CHLOROBENZENE | [Molecular Formula]
C6H3ClINO2 | [MDL Number]
MFCD11226294 | [MOL File]
5446-05-9.mol | [Molecular Weight]
283.45 |
| Chemical Properties | Back Directory | [Melting point ]
59℃ | [Boiling point ]
297.7±25.0 °C(Predicted) | [density ]
2.094±0.06 g/cm3(Predicted) | [storage temp. ]
Keep in dark place,Sealed in dry,2-8°C | [form ]
powder to crystal | [color ]
White to Light yellow |
| Hazard Information | Back Directory | [Synthesis]
General procedure for the synthesis of 4-chloro-1-iodo-2-nitrobenzene from 4-chloro-2-nitrobenzoic acid: 6.2 mg of silver sulfate, 21.8 mg of copper acetate, 12.5 mg of 2,9-dimethyl-1,10-phenanthroline, 40.3 mg of 4-chloro-2-nitrobenzoic acid, and 45 mg of iodine were sequentially added to a Silak reaction tube equipped with a magnetic stirrer. The reaction mixture was heated at 160°C for 24 hours under oxygen atmosphere. After completion of the reaction, the reaction was quenched by addition of distilled water and extracted three times with ethyl acetate. The organic phases were combined and concentrated to give 40.8 mg of 4-chloro-1-iodo-2-nitrobenzene in 72% yield. | [References]
[1] Journal of Organic Chemistry, 2016, vol. 81, # 7, p. 2794 - 2803
[2] Patent: CN107325002, 2017, A. Location in patent: Page/Page column 6; 7
[3] Organic and Biomolecular Chemistry, 2018, vol. 16, # 30, p. 5416 - 5421 |
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