| Identification | Back Directory | [Name]
(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 | [Synonyms]
Pentadienyltrimethylsilane
5-(Trimethylsilyl)-1,3-pentadiene
trimethyl(penta-2,4-dienyl)silane
Silane, trimethyl(2E)-2,4-pentadien-1-yl-
(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 | [Molecular Weight]
140.3 |
| Hazard Information | Back Directory | [Preparation]
5-Trimethylsilyl-1,3-pentadiene may be prepared in 85% yield by the reaction
of pentadienyllithium with chlorotrimethylsilane in THF at
room temperature.1–3 Generally the product is ≈95% (E) isomer
as judged by IR (strong band at 1000 cm?1) or NMR(trans
coupling constant of 15.2 Hz for proton at C-3, 5.92 ppm). |
|
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T&W GROUP
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Alfa Chemistry
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Fluorochem Ltd
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