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ChemicalBook--->CAS DataBase List--->80907-56-8

80907-56-8

80907-56-8 Structure

80907-56-8 Structure
IdentificationBack Directory
[Name]

[Ru(bpz)3][PF6]2
[CAS]

80907-56-8
[Synonyms]

[Ru(bpz)3][PF6]2
[Ru(bpz)3][PF6]2 95%
[Ru(bpz)3][PF6]2 AldrichCPR
Tris (2,2'-bipyrazine) ruthenium hexafluoroborate
Tris(2,2'-bipyrazine)ruthenium(II) hexafluorophosphate, 95%
[Molecular Formula]

C24H18F12N12P2Ru
[MDL Number]

MFCD27952557
[MOL File]

80907-56-8.mol
[Molecular Weight]

720.53
Chemical PropertiesBack Directory
[Melting point ]

162-210°C (The MP data is a DECOMP) (lit.)
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Powder
[color ]

red
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

28439000
Questions And AnswerBack Directory
[Reaction]

  1. Endoperoxide synthesis by photocatalytic aerobic [2+2+2] cycloadditions.
  2. Aerobic oxidation of a tertiary aliphatic amine under visible-light photocatalysis. Facile synthesis of methylenebridged bis-1,3-dicarbonyl compounds.
  3. Hydrophosphinylation of unactivated alkenes with secondary phosphine oxides under visible-light photocatalysis.
  4. Photooxygenation of aryl cyclopropanes via visible light photocatalysis.
Reactions of 80907-56-8_1
Reactions of 80907-56-8_2
Hazard InformationBack Directory
[Uses]

[Ru(bpz)3][PF6]2 may be employed as a photocatalyst during the preparation of cyclopentylamine derivatives, via visible light-assisted cycloaddition reaction of N-arylcyclopropylamines with styrene derivatives. It may also be employed for the photocatalytic synthesis of trans-substituted cyclohexene derivative.
[General Description]

[Ru(bpz)3][PF6]2 can be prepared from 2-iodopyrazine.
[reaction suitability]

core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst
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