| Identification | Back Directory | [Name]
(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE | [CAS]
824395-67-7 | [Synonyms]
(S,S)-Ph-BPE
(S,S)-Ph-BPE,BPE
(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE
1,2-Bis[(2S,5S)-2,5-diphenyl-1-phospholanyl]ethane, 97+%
(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane, min. 98%
(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE, KANATA PURITY
(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane,min.98%(S,S)-Ph-BPE | [Molecular Formula]
C34H36P2 | [MDL Number]
MFCD07369028 | [MOL File]
824395-67-7.mol | [Molecular Weight]
506.6 |
| Chemical Properties | Back Directory | [Melting point ]
144°C | [alpha ]
+182.7° (c 1.0, CH2Cl2) | [Boiling point ]
654.2±55.0 °C(Predicted) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [solubility ]
Sparingly Soluble (3.2E-5 g/L) (25°C). | [form ]
solid | [color ]
white | [Sensitive ]
Air Sensitive | [InChIKey]
VHHAZLMVLLIMHT-LXIGBKQFNA-N | [SMILES]
C([P@@]1[C@H](C2C=CC=CC=2)CC[C@H]1C1C=CC=CC=1)C[P@@]1[C@H](C2C=CC=CC=2)CC[C@H]1C1C=CC=CC=1 |&1:1,2,11,19,20,29,r| | [CAS DataBase Reference]
824395-67-7 |
| Questions And Answer | Back Directory | [Reaction]
- Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation.
- This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides.
- Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents.
- Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins.
- Ligand for asymmetric addition of allyl cyanide to ketones.
- Ligand for catalytic enantio- and diastereoselective aldol reaction of thioamides.
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| Company Name: |
Alfa Aesar
|
| Tel: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
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