1-甲基-2-哌啶甲醇(20845-34-5)核磁圖(1HNMR)
InChI:InChI=1S/C7H15NO/c1-8-5-3-2-4-7(8)6-9/h7,9H,2-6H2,1H3
InChIKey: HXXJMMLIEYAFOZ-UHFFFAOYSA-N
Smiles:N1(C)CCCCC1CO
-
Mass
MS-NW-5624
1-methyl-2-piperidinemethanol
C7H15NO (Mass of molecular ion: 129)
Source Temperature: 280 °C
Sample Temperature: 190 °C
Reservoir, 75 eV
15.0 2.3
18.0 1.7
27.0 3.3
28.0 2.8
29.0 1.9
30.0 1.9
31.0 1.4
39.0 3.2
41.0 5.5
42.0 19.0
43.0 2.8
44.0 9.1
53.0 1.1
54.0 1.3
55.0 4.5
56.0 2.3
57.0 2.9
67.0 1.7
68.0 2.9
69.0 1.1
70.0 21.7
71.0 1.3
82.0 3.5
83.0 1.4
84.0 2.1
94.0 1.0
96.0 5.3
97.0 1.9
98.0 100.0
99.0 7.1
110.0 2.5
111.0 2.7
400 MHz in CDCl3
90 MHz in CDCl3
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| 1H NMR |
399.65 MHz |
| C7 H15 N O
|
0.05 ml : 0.5 ml CDCl3
|
| 1-methyl-2-piperidinemethanol
|
 |
Assign. Shift(ppm)
A *1 3.761
B 3.52
C *1 3.485
D 2.862
E 2.296
F 2.113
G 1.942
J 1.754
K *2 1.65
L *2 1.61
M 1.55
N 1.52
P 1.276
ASSINED BY COSY.
J(A,C)=-11.0HZ.
J(A,G)=4.4HZ.
J(C,G)=2.9HZ.
90MHZ : HSP-03-583
|
Hz ppm Int.
1511.23 3.782 70
1506.84 3.771 72
1500.24 3.754 84
1495.85 3.743 82
1406.49 3.520 116
1398.93 3.501 89
1396.00 3.494 83
1387.82 3.473 66
1385.01 3.466 66
1151.73 2.882 33
1148.44 2.874 51
1146.48 2.869 35
1144.90 2.865 32
1141.72 2.857 31
1140.14 2.853 36
1137.57 2.847 54
1133.54 2.837 30
917.60 2.297 1000
858.28 2.148 51
854.98 2.140 44
846.68 2.119 102
843.38 2.111 94
835.08 2.090 54
831.79 2.082 52
783.94 1.962 41
779.91 1.952 43
776.37 1.943 39
773.07 1.935 48
769.04 1.925 48
708.86 1.774 37
707.89 1.772 40
705.57 1.766 32
704.10 1.762 33
699.83 1.752 30
698.61 1.749 31
696.17 1.742 42
695.07 1.740 44
692.75 1.734 35
666.38 1.668 30
663.82 1.662 32
661.99 1.657 32
657.96 1.647 30
656.25 1.643 36
654.54 1.638 46
652.95 1.634 64
651.98 1.632 59
650.39 1.628 66
648.80 1.624 70
647.34 1.620 49
645.63 1.616 50
642.82 1.609 33
639.89 1.602 62
637.33 1.595 53
635.86 1.592 83
634.03 1.587 67
632.69 1.584 87
631.10 1.580 70
628.91 1.574 105
627.69 1.571 96
625.00 1.564 69
623.54 1.561 63
621.09 1.555 52
616.94 1.544 87
613.28 1.535 62
612.55 1.533 64
610.23 1.527 39
609.13 1.525 38
608.15 1.522 31
605.22 1.515 48
604.00 1.512 48
601.44 1.505 33
599.24 1.500 30
526.73 1.318 30
518.55 1.298 38
514.28 1.287 61
509.89 1.276 30
506.23 1.267 32
501.95 1.256 51
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| 1H NMR |
89.56 MHz |
| C7 H15 N O
|
0.04 ml : 0.5 ml CDCl3
|
| 1-methyl-2-piperidinemethanol
|
|
Assign. Shift(ppm)
A *1 3.797
B *1 3.444
C 2.93
D 2.91
E 2.290
F 2.13
G 1.95
J 1.77
K 1.70 to 1.46
L 1.30
400MHZ : HSP-40-449
|
Hz ppm Int.
349.13 3.899 32
345.25 3.855 33
338.25 3.777 59
334.25 3.733 61
313.75 3.504 48
311.31 3.476 51
262.38 2.930 108
252.69 2.822 30
205.38 2.294 1000
177.63 1.984 35
150.31 1.679 60
149.56 1.670 59
148.81 1.662 55
144.88 1.618 91
142.25 1.589 85
141.44 1.580 74
140.44 1.569 82
139.38 1.557 76
136.56 1.525 57
134.25 1.499 38
132.13 1.476 32
129.13 1.442 32
129.00 1.441 32