What is the reaction mechanism of Trimethylsilyl trifluoromethanesulfonate?
May 11，2024
Studies on the mechanism of isomerisation of permethylated methyl d-glycopyranosides catalysed by Trimethylsilyl trifluoromethanesulfonate have shown that both cyclic and acyclic carbonyl ions appear to be intermediates in the isomerisation. The former appears to be a key intermediate in the formation of pyridine-type compounds as well as in the isomerisation of the α-glycosidic bond. On the other hand, the β-glycosidic bond seems to be isomerised mainly via acyclic carbonyl ions.
- Related articles
- Related Qustion
- Trimethylsilyl Trifluoromethanesulfonate: A Versatile Reagent in Modern Organic Synthesis Oct 24, 2024
Trimethylsilyl trifluoromethanesulfonate (TMSOTf) is a colorless moisture-sensitive liquid, it is frequent catalyzer or cationic initiator as silylation reagent in organic synthesis.
- Trimethylsilyl trifluoromethanesulfonate: applications in organic synthesis Jun 28, 2023
TMSOTf is a trifluoromethanesulfonate compound with a trimethylsilyl R-group. It is commonly used in organic synthesis and has similar reactivity to trimethylsilyl chloride
- What is Trimethylsilyl trifluoromethanesulfonate? Apr 14, 2021
Trimethylsilyl trifluoromethanesulfonate is composed by trifluoromethesulfonate and trimethylsilane group, under room pressure it is a colorless liquid.
1,7-Dimethylxanthine is a naturally occurring alkaloid compound that can enhance alertness and reduce drowsiness.....
Feb 27，2025API
Cholesterol is a waxy substance found in the blood of all humans and animals.....
May 11，2024Biochemical Engineering
Trimethylsilyl trifluoromethanesulfonate
27607-77-8You may like
Trimethylsilyl trifluoromethanesulfonate manufacturers
- Vinyltriisopropenoxysilane
-
- $150.00 / 1kg
- 2025-05-07
- CAS:27607-77-8
- Min. Order: 1kg
- Purity: 99%
- Supply Ability: 500kg
- Trimethylsilyl trifluoromethanesulfonate
-
- $0.00 / 1KG
- 2025-05-06
- CAS:27607-77-8
- Min. Order: 1KG
- Purity: 98%min
- Supply Ability: 30tons/month
- Trimethylsilyl trifluoromethanesulfonate
-
- $0.00 / 1KG
- 2025-04-15
- CAS:27607-77-8
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 500000kg