1-(2-BROMOBENZYL)PYRROLIDINE synthesis
- Product Name:1-(2-BROMOBENZYL)PYRROLIDINE
- CAS Number:91130-46-0
- Molecular formula:C11H14BrN
- Molecular Weight:240.14
18982-54-2
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609-36-9
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91130-46-0
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Yield:91130-46-0 90%
Reaction Conditions:
with bis[dichloro(pentamethylcyclopentadienyl)iridium(III)];sodium hydrogencarbonate in toluene at 110; for 96 h;Inert atmosphere;
Steps:
General Procedure for the Preparation of 3
General procedure: To a solution of [Cp*IrCl2]2 (0.0025 mmol), amino acid 2(0.65 mmol), and NaHCO3 (0.05 mmol) in toluene (3 mL) under an atmosphere of argon was added alcohol 1 (0.5mmol). The resulting mixture was stirred at 110 °C for a certain period of time. The reaction mixture was cooled tor.t., and H2O (5 mL) was then added. The resulting solution was extracted with EtOAc. Purification on silicon gel afforded the desired products 3.
References:
Wu, Jiashou;Jiang, Huajiang;Chen, Dingben;Shen, Jianfen;Zhao, Datong;Xiang, Jing;Zhou, Qizhong [Synlett,2014,vol. 25,# 4,art. no. ST-2013-W0920-L,p. 539 - 542]
123-75-1
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3433-80-5
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$10.00/1g
91130-46-0
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$57.50/250mg
7154-66-7
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91130-46-0
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$57.50/250mg
3433-80-5
321 suppliers
$10.00/1g
91130-46-0
27 suppliers
$57.50/250mg
124461-27-4
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$116.00/1g
91130-46-0
27 suppliers
$57.50/250mg