1,4-Bis(trans-styryl)benzene synthesis
- Product Name:1,4-Bis(trans-styryl)benzene
- CAS Number:1608-41-9
- Molecular formula:C22H18
- Molecular Weight:282.38
1449-46-3
317 suppliers
$5.00/1g
623-27-8
547 suppliers
$5.00/10g
1608-41-9
33 suppliers
$110.00/250 mg
Yield: 65%
Reaction Conditions:
with C11H20N3(1+)*C2F6NO4S2(1-) at 70; for 7 h;Ionic liquid;Inert atmosphere;Wittig Olefination;
Steps:
2.5.2. Double Wittig
General procedure: An oven-dried reaction tube equipped with a magnetic stirrer barwas charged with a mixture of dialdehyde (1.3 mmol), benzyltriphenylphosphonium bromide (2.2 mmol), [PAIM][NTf2] (4 mmol)and [BMIM][PF6] (7 mL). The reaction mixture was stirred and heatedat 60-70 °C under a nitrogen atmosphere for 7-8 h. After completion(TLC monitoring) the crude reaction mixture was extracted 3 times with hexane/EtOAc (80:20), dried (magnesium sulfate), and the solvent was removed under vacuum to furnish the crude product which was then purified by flash column chromatography with hexane/ethyl acetate (80:20).
References:
Savanur, Hemantkumar M.;Kalkhambkar, Rajesh G.;Laali, Kenneth K. [Applied Catalysis A: General,2017,vol. 543,p. 150 - 161]
100-42-5
653 suppliers
$19.00/25mL
106-37-6
487 suppliers
$9.00/5g
1608-41-9
33 suppliers
$110.00/250 mg
100-42-5
653 suppliers
$19.00/25mL
624-38-4
388 suppliers
$6.00/5g
1608-41-9
33 suppliers
$110.00/250 mg
1849-27-0
101 suppliers
$35.79/1g
1608-41-9
33 suppliers
$110.00/250 mg
100-42-5
653 suppliers
$19.00/25mL
624-38-4
388 suppliers
$6.00/5g
1608-41-9
33 suppliers
$110.00/250 mg
![Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy-](/CAS/20210305/GIF/1000210-73-0.gif)
1000210-73-0
0 suppliers
inquiry