N-NONANE synthesis
- Product Name:N-NONANE
- CAS Number:111-84-2
- Molecular formula:C9H20
- Molecular Weight:128.26
67-66-3
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$33.60/500ml
38841-98-4
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$114.00/100ml
111-84-2
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$24.50/1000mg
629-78-7
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$15.00/25g
Yield:111-84-2 9% ，629-78-7 90.6%
Reaction Conditions:
with C31H37ClN3NiO2(1-)*Li(1+) in tetrahydrofuran at 25; for 0.333333 h;Inert atmosphere;Overall yield = 99.6 %;
Steps:
2.5 Cross coupling of CHCl3 and CCl4 with Grignard reagent
General procedure: Cross-coupling reactions of Grignard reagents with CHCl3 and CCl4 were performed according to the following general method. Catalyst 2 (1 mg, 1.74 μmol) in 1 mL THF was added using a gas-tight syringe to a 5 mL round bottom flask purged with N2. To this solution 2 M n-butylmagnesium chloride in THF (0.63 mL, 1.26 mmol) was added. CHCl3 (34 μL, 0.42 mmol) was added to the reaction mixture. In the case of reactions with CCl4 (40 μL, 0.42 mmol), 1.68 mmol of Grignard reagent was added. Samples were collected for analysis after 20 min. At the end of the reaction, excess Grignard reagent was destroyed using methanol and the reaction products were analyzed by GC-MS using an internal standard to quantify product formation.
References:
Gartia, Yashraj;Nasini, Udaya Bhasker;Ghosh, Anindya;Biswas, Abhijit;Stadler, Matthew [Journal of Molecular Catalysis A: Chemical,2012,vol. 363-364,p. 322 - 327,6]
112-31-2
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$6.00/10g
111-84-2
230 suppliers
$24.50/1000mg
38284-28-5
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111-84-2
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$24.50/1000mg
67-66-3
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$33.60/500ml
693-04-9
198 suppliers
$11.00/5g
111-84-2
230 suppliers
$24.50/1000mg
17312-63-9
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56-23-5
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$25.00/10ml
693-04-9
198 suppliers
$11.00/5g
111-84-2
230 suppliers
$24.50/1000mg
17312-63-9
5 suppliers
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