| Identification | More | [Name]
2-Amino-4-methoxy-6-methyl-1,3,5-triazine | [CAS]
1668-54-8 | [Synonyms]
2-AMINO-4-METHOXY-6-METHYL-1,3,5-TRIAZINE
2-AMINO-4-METHOXY-6-METHYL-S-TRIAZINE
2-AMINO-4-METHYL-6-METHOXY-1,3,5-TRIAZINE
4-METHOXY-6-METHYL-1,3,5-TRIAZIN-2-YLAMINE
TIMTEC-BB SBB004163
2-amino-4-methoxy-6-methyl-s-triazin
2-methyl-4-amino-6-methoxy-s-triazine
5-triazin-2-amine,4-methoxy-6-methyl-3
cv399
2-AMINO-4-METHOXY-6-METHYL-1,3,5-TRIAZIN
2-Amino-4-methyl-6-methoxy-s-triazine
4-Methoxy-6-methyl-1,3,5-triazin-2-amine
CGA-150829
2-Methoxy-4-methyl-1,3,5-triazine-6-amine
4-Methyl-6-methoxy-1,3,5-triazine-2-amine
4-Methyl-6-methoxy-2-amino-1,3,5-triazine
2-Amino-4-methoxy-6-methyl-1,3,5-trazine | [EINECS(EC#)]
216-790-7 | [Molecular Formula]
C5H8N4O | [MDL Number]
MFCD00052764 | [Molecular Weight]
140.14 | [MOL File]
1668-54-8.mol |
| Chemical Properties | Back Directory | [Appearance]
off-white to light yellow powder | [Melting point ]
258-261 °C(lit.) | [Boiling point ]
114℃ | [density ]
1.2945 (rough estimate) | [refractive index ]
1.8300 (estimate) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2–8 °C | [solubility ]
Chloroform (Slightly), DMSO (Slightly) | [form ]
Solid | [pka]
3.65±0.10(Predicted) | [color ]
White to Light Yellow | [InChI]
InChI=1S/C5H8N4O/c1-3-7-4(6)9-5(8-3)10-2/h1-2H3,(H2,6,7,8,9) | [InChIKey]
NXFQWRWXEYTOTK-UHFFFAOYSA-N | [SMILES]
N1=C(C)N=C(OC)N=C1N | [CAS DataBase Reference]
1668-54-8(CAS DataBase Reference) | [EPA Substance Registry System]
1668-54-8(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
1
| [RTECS ]
XY3193000
| [HazardClass ]
IRRITANT | [HS Code ]
29336990 | [Toxicity]
LD50 oral in mouse: 1010mg/kg |
| Hazard Information | Back Directory | [Chemical Properties]
off-white to light yellow powder | [Uses]
2-Amino-4-methoxy-6-methyl-1,3,5-triazine may be used in the synthesis of thifensulfuron. | [Definition]
ChEBI: A monoamino-1,3,5-triazine that is 1,3,5-triazin-2-amine substituted by a methoxy group at position 4 and a methyl group at position 6. It is a metabolite of the herbicide thifensulfuron-methyl. | [General Description]
2-Amino-4-methoxy-6-methyl-1,3,5-triazine is formed during the photocatalytic decomposition of sulfonylurea (Sus) herbicide. It is also formed as a thermal decomposition product of chlorsulfuron (a sulfonylurea herbicide) and has been determined by GC using nitrogen-phosphorus detection (NPD). | [Synthesis]
Example 2: Acetamidine hydrochloride (9.5 g) was added to a solution of methanol (50 mL) and potassium hydroxide particles (6.8 g) pre-cooled to 10°C. Subsequently, dimethyl N-cyanoimido carbonate (11.4 g) was dissolved in 40 mL of methanol and this solution was slowly added dropwise to the above reaction mixture. After the dropwise addition was completed, the reaction mixture was stirred continuously at 25°C for 2 hours. Upon completion of the reaction, the mixture was poured into 40 mL of ice water to quench the reaction. The resulting solid crystals were collected by filtration and washed sequentially with water and methanol. Finally, the product was dried at 70 °C overnight to afford 11.8 g of 2-amino-4-methyl-6-methoxy-1,3,5-triazine in 84% yield. | [References]
[1] Patent: US5070199, 1991, A |
|
|