| Identification | More | [Name]
SILVER BENZOATE | [CAS]
532-31-0 | [Synonyms]
BENZOIC ACID SILVER SALT
SILVER BENZOATE
SILVER(I) BENZOATE
Benzoic acid, silver(1+) salt
benzoicacid,silver(1++)salt
Silver benzoate (AgOBz)
Silver(1+) benzoate
Silver benzoate hydrate
BENZOIC ACID SILVER
Silver(I) benzoate, 98+%
AgOBz
Benzoic acid silver(I) salt | [EINECS(EC#)]
208-533-2 | [Molecular Formula]
C7H5AgO2 | [MDL Number]
MFCD00013030 | [Molecular Weight]
228.98 | [MOL File]
532-31-0.mol |
| Chemical Properties | Back Directory | [Appearance]
Off-White Crystalline Powder | [Melting point ]
>188°C (dec.) | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
cold water: soluble385 part(lit.) | [form ]
Powder | [color ]
White to cream or gray | [Water Solubility ]
Insoluble in water. | [Sensitive ]
Light Sensitive | [InChI]
InChI=1S/C7H6O2.Ag/c8-7(9)6-4-2-1-3-5-6;/h1-5H,(H,8,9); | [InChIKey]
CLDWGXZGFUNWKB-UHFFFAOYSA-M | [SMILES]
C(C1C=CC=CC=1)(=O)O.[Ag] | [CAS DataBase Reference]
532-31-0(CAS DataBase Reference) | [EPA Substance Registry System]
Benzoic acid, silver(1+) salt (532-31-0) |
| Safety Data | Back Directory | [Safety Statements ]
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [TSCA ]
Yes | [HS Code ]
28432900 |
| Hazard Information | Back Directory | [Chemical Properties]
Off-White Crystalline Powder | [Application]
Silver benzoate was used in the synthesis of triphenyltinbenzoate. It is an efficient catalytic system for the reaction of carbon dioxide with various ketones. | [Uses]
Silver benzoate was used in the synthesis of triphenyltinbenzoate. | [Uses]
Silver benzoate is an aromatic salt that is used as a catalyst to prepare β-amino acids (such as N-Acetyl-β-alanine [A168070]) from α-amino acids (such as D-Alanine [A480995]). Silver benzoate is also used as a catalyst in Wolff rearrangement reactions. | [Reactions]
Silver benzoate reacts with bromine in CCl4 refluxing to form C6H5Br This reaction is called Hunsdiecker reaction. | [General Description]
Silver benzoate along with 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene (MTBD) is an efficient catalytic system for the reaction of carbon dioxide with various ketones. | [Synthesis]
Silver benzoate can be obtained by reacting silver nitrate and sodium benzoate:
AgNO3 + PhCOONa → PhCOOAg↓ + NaNO3
Reaction: Mix an equimolar amount of silver nitrate solution with sodium benzoate solution to precipitate silver benzoate. Washed with water and dried in a vacuum desiccator. |
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