| Identification | More | [Name]
2-Nitrobenzyl alcohol | [CAS]
612-25-9 | [Synonyms]
2-NITROBENZYL ALCOHOL
(2-NITROPHENYL)METHANOL
LABOTEST-BB LT01997457
O-NITROBENZYL ALCOHOL
O-NITROPHENYLCARBINOL
RARECHEM AL BD 0186
2-nitro-benzenemethano
2-nitrobenzenemethanol
Benzyl alcohol, o-nitro-
o-hydroxymethylnitrobenzene
o-nitro-benzylalcoho
O-Nitrobenzyl alcohol(2-Nitrobenzyl alcohol)
O-nitrobenzyle alcohol
O-NTROBENZYLALCOHOL 99%
2-Nitrobenzyalcohol
oNBAIc
2-Nitrobenzylalcohol,97%
Benzenemethanol, 2-nitro-
2-Nitrobenzyl alcohol 98%
2-NITROBENZYL ALCOHOL/O-NITROPHENYLCARBINOL | [EINECS(EC#)]
210-302-6 | [Molecular Formula]
C7H7NO3 | [MDL Number]
MFCD00007186 | [Molecular Weight]
153.14 | [MOL File]
612-25-9.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
69-72 °C(lit.)
| [Boiling point ]
270 °C(lit.)
| [density ]
1.3386 (rough estimate) | [refractive index ]
1.5030 (estimate) | [Fp ]
168°C/20mm | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
soluble in Methanol | [form ]
Crystalline Powder | [pka]
13.77±0.10(Predicted) | [color ]
Beige to beige-brown | [Water Solubility ]
Soluble in water 5000 mg/L 20 deg Celsius. | [Sensitive ]
Light Sensitive | [BRN ]
2046649 | [InChIKey]
BWRBVBFLFQKBPT-UHFFFAOYSA-N | [CAS DataBase Reference]
612-25-9(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzenemethanol, 2-nitro-(612-25-9) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,C,F | [Risk Statements ]
R11:Highly Flammable.
R34:Causes burns. | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S16:Keep away from sources of ignition-No smoking . | [RIDADR ]
UN 2811 6.1/PG 3
| [WGK Germany ]
3
| [RTECS ]
DP0657050
| [Hazard Note ]
Irritant | [HS Code ]
29062900 |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Synthesis]
GENERAL METHODS: The substrate (1 mmol, CAS: 62673-13-6) was mixed with ionic liquid [Dsim]HSO4 (6.5 mg, ~0.02 mmol) in methanol (2 mL) and the reaction was stirred at room temperature. The reaction process was monitored by thin layer chromatography (TLC). After completion of the reaction, the solvent was removed by evaporation and water (1 mL) was added to the residue with vigorous stirring. The almost pure o-nitrobenzyl alcohol product was obtained by decantation separation. The structure of the product was characterized by infrared spectroscopy (IR) and nuclear magnetic resonance (NMR) data. The ionic liquid was recovered for reuse after vacuum drying at 65 °C to remove water. | [storage]
Light-sensitive. Harmful if swallowed or inhaled. | [References]
[1] Bulletin of the Chemical Society of Japan, 2000, vol. 73, # 12, p. 2775 - 2778
[2] Journal of Molecular Catalysis A: Chemical, 2012, vol. 365, p. 15 - 23
[3] Journal of Chemical Research, 2006, # 1, p. 29 - 31
[4] Phosphorus, Sulfur and Silicon and the Related Elements, 2008, vol. 183, # 1, p. 168 - 177
[5] Journal of the Chinese Chemical Society, 2008, vol. 55, # 5, p. 943 - 946 |
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