Identification | More | [Name]
BISMUTH(III) BROMIDE | [CAS]
7787-58-8 | [Synonyms]
BISMUTH BROMIDE BISMUTH(III) BROMIDE BISMUTH TRIBROMIDE bismuth(ii)bromide Bismuthine, tribromo- Bismuthine,tribromo- tribromo-bismuthin BISMUTH(III) BROMIDE, 98+% BISMUTH(III) BROMIDE, 99.999% Bismuth(III)bromide,99%(metalsbasis) Tribromobismuthine | [EINECS(EC#)]
232-121-1 | [Molecular Formula]
BiBr3 | [MDL Number]
MFCD00014195 | [Molecular Weight]
448.69 | [MOL File]
7787-58-8.mol |
Chemical Properties | Back Directory | [Appearance]
Light yellow-gray crystals or crystalline powder | [Melting point ]
218°C | [Boiling point ]
453°C | [density ]
5.7 g/mL at 25 °C(lit.)
| [Fp ]
453°C | [solubility ]
reacts with H2O; soluble in dilacid, acetone; insoluble in ethanol | [form ]
powder
| [color ]
Yellow | [Water Solubility ]
Decomposes in water. | [Sensitive ]
Hygroscopic | [Merck ]
13,1258 | [InChI]
InChI=1S/Bi.3BrH/h;3*1H/q+3;;;/p-3 | [InChIKey]
TXKAQZRUJUNDHI-UHFFFAOYSA-K | [SMILES]
[Bi](Br)(Br)Br | [CAS DataBase Reference]
7787-58-8(CAS DataBase Reference) | [EPA Substance Registry System]
Bismuthine, tribromo- (7787-58-8) |
Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3260 8/PG 2
| [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
2827590000 |
Hazard Information | Back Directory | [Chemical Properties]
Light yellow-gray crystals or crystalline powder | [Uses]
By virtue of their low toxicity and high versatility, hold considerable promise as catalysts for various organic transformations | [Uses]
It catalyzes the formation of cyclic carbonates. | [Production Methods]
Bismuth powder is placed in a retort, Br2 is poured over it, and the mixture is allowed to stand for a few days and then distilled. It is also possible to heat Br2 with Bi in a round-bottom flask equipped with a reflux condenser. Purification is by vacuum distillation. | [reaction suitability]
reagent type: catalyst core: bismuth |
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